Bis(pentane-2,4-dionato-κ2 O,O′)bis[4,4,5,5-tetramethyl-2-(4-pyridyl)imidazoline-1-oxyl 3-oxide-κN 2]manganese(II)
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چکیده
The title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))(2)], is isostructural with its Ni(II)-containing analogue [Hao, Mu & Kong (2008 ▶). Acta Cryst. E64, m957]. The asymmetric unit comprises one-half of the mol-ecule and the Mn(II) ion is located on an inversion centre. The coordination geometry around the Mn(II) ion is slightly distorted octa-hedral, comprised of four O and two N atoms, in which the four O atoms in the equatorial plane come from two pentane-2,4-dionate ligands and the two N atoms in the axial coordination sites from 4,4,5,5-tetra-methyl-2-(4-pyrid-yl)imidazoline-1-oxyl 3-oxide.
منابع مشابه
Bis(pentane-2,4-dionato)bis[2-(4-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide]nickel(II)
In the title compound, [Ni(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the Ni(II) cation is hexa-coordinated by four O and two N atoms, showing a slightly distorted octa-hedral geometry. The Ni(II) cation lies on an inversion centre, as a consequence of which the asymmetric unit comprises one half-mol-ecule. The four O atoms belonging to two pentane-2,4-dionate ligands lie in the equatorial plane an...
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